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Vinyl copper lithium.
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Vinyllithium is an organolithium compound with the formula lic 2 h 3.
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It is a reagent in synthesis of organic compounds.
Vinyl and aryl grignard reagents couple with primary alkyl halides in the presence of a catalytic amount of a copper i halide salt.
For example lithium divinylcuprate is alkylated.
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The use of li 2 cucl 4 rather than simple copper i halide salts cux improves yields of these coupling reactions.
A very popular and often complementary alternative to the foregoing vinyllithium chemistry is the use of lithium divinyl or diaryl cuprate species r 2 culi which also can be alkylated using primary alkyl bromides or iodides but often only in the presence of various additives typically a stabilizing phosphine ligand and the correct solvent.
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A colorless or white solid it is encountered mainly as a solution in tetrahydrofuran thf.
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